Hydrogen bonds in carboxylic acid-carboxylate systems in solution.: 1.: In anhydrous, aprotic media

被引：27

作者：

Brück, A ^{[1
]}

McCoy, LL ^{[1
]}

Kilway, KV ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 14期

关键词：

D O I：

10.1021/ol005776j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

GRAPHICS Preliminary NMR studies on hydrogen bonding of carboxylic acid-carboxylate systems in an anhydrous, aprotic solvent are presented. In all cases, a tow-field resonance (16-20 ppm) indicative of strong hydrogen bonding was observed. From these results, it seems probable that this characteristic downfield shift should be exhibited by all carboxylic acid-carboxylate systems in anhydrous, aprotic media.

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页码：2007 / 2009

页数：3

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