Modulating the luminescence of an iridium(III) complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand with Zn2+ cations

被引：52

作者：

Araya, Juan C. ^{[2
]}

Gajardo, Juana ^{[2
]}

Moya, Sergio A. ^{[2
]}

Aguirre, Pedro ^{[3
]}

Toupet, Loic ^{[4
]}

Williams, J. A. Gareth ^{[5
]}

Escadeillas, Muriel ^{[1
]}

Le Bozec, Hubert ^{[1
]}

Guerchais, Veronique ^{[1
]}

机构：

[1] Univ Rennes 1, UMR Sci Chim Rennes 6226, CNRS, F-35042 Rennes, France

[2] Univ Santiago Chile, Fac Quim & Biol, Santiago, Chile

[3] Univ Chile, Fac Ciencias Quim & Farmaceut, Santiago, Chile

[4] Univ Rennes 1, UMR 6626, Inst Phys Rennes, CNRS, F-35042 Rennes, France

[5] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 01期

关键词：

PHOTOPHYSICAL PROPERTIES; ELECTROCHEMICAL PROPERTIES; CYCLOMETALATED COMPLEXES; POLYPYRIDINE COMPLEXES; COORDINATION-COMPOUNDS; SATURATED ANALOGS; ZINC IONS; TERPYRIDINE; EMISSION; SENSOR;

D O I：

10.1039/b9nj00515c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel iridium complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand was synthesized and its optical properties studied. The presence of Zn2+ ions specifically perturbs the excited state, giving rise to a blue-shifted absorption and emission, and a shorter luminescence lifetime.

引用

页码：21 / 24

页数：4

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