Bond valence sums for YBCO and CLBLCO

被引:3
作者
Eckstein, Y
Kuper, CG [1 ]
机构
[1] Technion Israel Inst Technol, Dept Phys, IL-32000 Haifa, Israel
[2] Technion Israel Inst Technol, Crown Ctr Supercond, IL-32000 Haifa, Israel
来源
PHYSICA B | 2000年 / 284卷
基金
以色列科学基金会;
关键词
bond valence sums; oxidation state; (CaLa)(BaLa)(2)Cu3O6+x; YBaCuO;
D O I
10.1016/S0921-4526(99)01966-3
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We present bond-valence sum (BVS) calculations for YBa2Cu3Oy ("YBCO"), using the data of Cava et al., and for (CaxLa1 - x)(Ba1.75 - xLa0.25 + x)Cu3Oy ("CLBLCO"), using the refined neutron diffraction data of Chmaissen et al. It has been conjectured that from the BVS results one can estimate the concentration of mobile charge carriers in the CuO2 plane. We have used both the method of Brown ct al, and that of Tallon ct al. for estimating this number. The difference between the two methods will be discussed, and the conjecture will be critically reviewed. (C) 2000 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:403 / 404
页数:2
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