SANS study of associative triblocks in microemulsion solutions

被引:5
作者
Bhatia, SR
Russel, WB [1 ]
Lal, J
机构
[1] Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA
[2] Argonne Natl Lab, Intense Pulsed Neutron Source, Argonne, IL 60439 USA
关键词
D O I
10.1107/S0021889899012236
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Small-angle neutron scattering was used to study the interactions between AOT/water/decane microemulsions and poly( ethylene oxide)-polyisoprene-poly(ethylene oxide) triblocks. The interdroplet spacing seems to be independent of molecular weight and polymer concentration. Scattering experiments on the polyisoprene layer yield a high q exponent of -1.6 +/- 0.1, indicating that the layer is swollen by decane.
引用
收藏
页码:614 / 617
页数:4
相关论文
共 16 条
[1]
Phase behavior and viscoelasticity of AOT microemulsions containing triblock copolymers [J].
Batra, U ;
Russel, WB ;
Pitsikalis, M ;
Sioula, S ;
Mays, JW ;
Huang, JS .
MACROMOLECULES, 1997, 30 (20) :6120-6126
[2]
BHATIA S, 1999, UNPUB
[4]
Christ S, 1993, PROG COLL POL SCI S, V93, P203
[5]
ON THE DYNAMICS OF EQUILIBRIUM NETWORKS - POE-B-PI-B-POE COPOLYMERS IN H2O AOT ISOOCTANE WATER-IN-OIL MICROEMULSIONS [J].
FLEISCHER, G ;
STIEBER, F ;
HOFMEIER, U ;
EICKE, HF .
LANGMUIR, 1994, 10 (06) :1780-1785
[6]
Goulian M, 1996, J PHYS II, V6, P543, DOI 10.1051/jp2:1996105
[7]
Higgins J.S., 1994, POLYM NEUTRON SCATTE
[8]
Viscosity effects of a graft copolymer with a hydrophobic backbone and hydrophilic side chains in a water AOT cyclohexane oil continuous microemulsion [J].
Holmberg, A ;
Piculell, L ;
Wesslen, B .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (02) :462-464
[9]
TEMPERATURE-DEPENDENCE OF SIZE AND POLYDISPERSITY IN A 3-COMPONENT MICRO-EMULSION BY SMALL-ANGLE NEUTRON-SCATTERING [J].
KOTLARCHYK, M ;
CHEN, SH ;
HUANG, JS .
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (17) :3273-3276
[10]
LAL J, 1995, MATER RES SOC SYMP P, V366, P427