Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation

被引：53

作者：

Armstrong, David R.

Clegg, William

Dale, Sophie H.

Graham, David V.

Hevia, Eva

Hogg, Lorna M.

Honeyman, Gordon W.

Kennedy, Alan R.

Mulvey, Robert E. ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XN, Lanark, Scotland

[2] Univ Newcastle Upon Tyne, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 06期

关键词：

D O I：

10.1039/b613655a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of (Bu2Zn)-Bu-t, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported.

引用

页码：598 / 600

页数：3

共 11 条

[1] Sodium dialkyl-amidozincates: Alkyl or amido bases? An experimental and theoretical case study [J].