Solvent System for Steady State Electrospinning of Polyamide 6.6

被引:44
作者
De Vrieze, Sander [1 ]
Westbroek, Philippe [1 ]
Van Camp, Tamara [1 ]
De Clerck, Karen [1 ]
机构
[1] Univ Ghent, Dept Text, B-9052 Ghent, Belgium
关键词
nanofibres; electrospinning; steady state; NANOFIBERS; NYLON-6; FABRICATION;
D O I
10.1002/app.30331
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
A mixture of formic acid/acetic acid makes it possible to electrospin polyamide 6.6 in steady state conditions. Steady state conditions are essential in nozzle electrospinning to generate a stable process which fabricates reproducible material, permitting industrial upscaling. This study shows that only a limited mixture range of formic acid/acetic acid allows electrospinning of polyamide 6.6 in steady state. Furthermore, the weight concentration in solution; the tip to collector distance and the flow rate have been changed to control the average diameter of the nanofibres. The average diameter increases by increasing weight concentration in solution, increasing volume fraction of acetic acid in the mixture, increasing tip to collector distance and increasing flow rate. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 115: 837-842, 2010
引用
收藏
页码:837 / 842
页数:6
相关论文
共 20 条
[1]
Anton F., 1934, US patent, Patent No. [US1975504A, 1975504, 1975504A]
[2]
Thermal and mechanical properties of electrospun PMMA, PVC, Nylon 6, and Nylon 6,6 [J].
Carrizales, Clarisa ;
Pelfrey, Sean ;
Rincon, Roman ;
Eubanks, Thomas M. ;
Kuang, Anxiu ;
McClure, Michael J. ;
Bowlin, Gary L. ;
Macossay, Javier .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2008, 19 (02) :124-130
[3]
Electrospun nanofibers: Internal structure and intrinsic orientation [J].
Dersch, R ;
Liu, TQ ;
Schaper, AK ;
Greiner, A ;
Wendorff, JH .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (04) :545-553
[4]
Fang ZX, 2004, ACTA POLYM SIN, P500
[5]
Preparation and characterization of core-shell structured nanofibers by coaxial electrospinning [J].
Han, Xiaojian ;
Huang, Zhengming ;
He, Chuanglong ;
Liu, Ling .
HIGH PERFORMANCE POLYMERS, 2007, 19 (02) :147-159
[6]
Theory and kinematic measurements of the mechanics of stable electrospun polymer jets [J].
Helgeson, Matthew E. ;
Grammatikos, Kristie N. ;
Deitzel, Joseph M. ;
Wagner, Norman J. .
POLYMER, 2008, 49 (12) :2924-2936
[7]
Fabrication of MWNTs/nylon conductive composite nanofibers by electrospinning [J].
Jeong, J. S. ;
Jeon, S. Y. ;
Lee, T. Y. ;
Park, J. H. ;
Shin, J. H. ;
Alegaonkar, P. S. ;
Berdinsky, A. S. ;
Yoo, J. B. .
DIAMOND AND RELATED MATERIALS, 2006, 15 (11-12) :1839-1843
[8]
John D, 1998, LANGES HDB CHEM PHYS
[9]
The effect of molecular weight and the linear velocity of drum surface on the properties of electrospun poly(ethylene terephthalate) nonwovens [J].
Kim, KW ;
Lee, KH ;
Khil, MS ;
Ho, YS ;
Kim, HY .
FIBERS AND POLYMERS, 2004, 5 (02) :122-127
[10]
Use of electrospun nanofiber web for protective textile materials as barriers to liquid penetration [J].
Lee, Seungsin ;
Obendorf, S. Kay .
TEXTILE RESEARCH JOURNAL, 2007, 77 (09) :696-702