Synchronization and pattern formation in electrochemical oscillators: Model calculations

被引:47
作者
Mazouz, N [1 ]
Krischer, K [1 ]
Flatgen, G [1 ]
Ertl, G [1 ]
机构
[1] MAX PLANCK GESELL,FRITZ HABER INST,D-14195 BERLIN,GERMANY
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 14期
关键词
D O I
10.1021/jp962659q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
There exist many experimental examples of spatial pattern formation in electrochemical systems. Using a recently proposed model, we present numerical simulations of the spatio-temporal behavior in the bistable and oscillatory regime. The simulations reveal that for some parameter regimes only spatially inhomogeneous solutions exist. The impact of the system parameters on the spatial coupling as well as on the existence of patterns is elaborated. The predictions coincide with experimental results for a simple electrochemical reaction, the reduction of peroxodisulfate.
引用
收藏
页码:2403 / 2410
页数:8
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