Preparation and characterization of CeO2/TiO2 catalysts for selective catalytic reduction of NO with NH3

被引:243
作者
Gao, Xiang [1 ]
Jiang, Ye [1 ]
Fu, Yincheng [1 ]
Zhong, Yi [1 ]
Luo, Zhongyang [1 ]
Cen, Kefa [1 ]
机构
[1] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China
基金
美国国家科学基金会;
关键词
Selective catalytic reduction; NO reduction; CeO2/TiO2; Preparation; VANADIA-TITANIA CATALYSTS; NITRIC-OXIDE; REDOX PROPERTIES; AMMONIA; OXIDATION; ALUMINA; FTIR; SCR;
D O I
10.1016/j.catcom.2009.11.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CeO2/TiO2 catalysts were prepared by three methods, and their activities for SCR of NO with NH3 were investigated in the presence Of O-2. The experimental results indicate that the catalysts prepared by the single step sol-gel method have the best SCR activity and SO2 resistance regardless of the concentration of NO or SO2. High surface area and good redox ability are important to the catalytic activity, while the strong interaction between ceria and titania as well as high concentration of amorphous or highly dispersed nano-crystalline ceria should be the reason for the excellent performance of the catalyst prepared by the single step sot-gel method. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:465 / 469
页数:5
相关论文
共 22 条
[1]   Gold-vanadia catalysts supported on ceria-alumina for complete benzene oxidation [J].
Andreeva, D ;
Nedyalkova, R ;
Ilieva, L ;
Abrashev, MV .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 52 (03) :157-165
[2]   Characterization of ceria-coated alumina carrier [J].
Damyanova, S ;
Perez, CA ;
Schmal, M ;
Bueno, JMC .
APPLIED CATALYSIS A-GENERAL, 2002, 234 (1-2) :271-282
[3]   Effect of oxygen concentration on the NOx reduction with ammonia overV2O5-WO3/TiO2 catalyst [J].
Djerad, S ;
Crocoll, M ;
Kureti, S ;
Tifouti, L ;
Weisweiler, W .
CATALYSIS TODAY, 2006, 113 (3-4) :208-214
[4]   Oxidation of sulfur dioxide to sulfur trioxide over supported vanadia catalysts [J].
Dunn, JP ;
Koppula, PR ;
Stenger, HG ;
Wachs, IE .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 19 (02) :103-117
[5]   Spectroscopic studies of interfacial structures of CeO2-TiO2 mixed oxides [J].
Fang, Jun ;
Bi, Xinzhen ;
Si, Dejun ;
Jiang, Zhiquan ;
Huang, Weixin .
APPLIED SURFACE SCIENCE, 2007, 253 (22) :8952-8961
[6]   The activity and characterization of CeO2-TiO2 catalysts prepared by the sol-gel method for selective catalytic reduction of NO with NH3 [J].
Gao, Xiang ;
Jiang, Ye ;
Zhong, Yi ;
Luo, Zhongyang ;
Cen, Kefa .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 174 (1-3) :734-739
[7]   The activity and characterization of sol-gel Sn/Al2O3 catalyst for selective catalytic reduction of NOx in the presence of oxygen [J].
Li, JH ;
Hao, JM ;
Fu, LX ;
Liu, ZM ;
Cui, XY .
CATALYSIS TODAY, 2004, 90 (3-4) :215-221
[8]   The highly active catalysts of nanometric CeO2-supported cobalt oxides for soot combustion [J].
Liu, Jian ;
Zhao, Zhen ;
Wang, Jiqiu ;
Xu, Chunming ;
Duan, Aijun ;
Jiang, Guiyuan ;
Yang, Qing .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 84 (1-2) :185-195
[9]   The promoting role of rare earth oxides on Fe-exchanged TiO2-pillared clay for selective catalytic reduction of nitric oxide by ammonia [J].
Long, RQ ;
Yang, RT .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 27 (02) :87-95
[10]   Structure and redox properties of CexTi1-xO2 solid solution [J].
Luo, MF ;
Chen, J ;
Chen, LS ;
Lu, JQ ;
Feng, Z ;
Li, C .
CHEMISTRY OF MATERIALS, 2001, 13 (01) :197-202