Breathing Transitions in MIL-53(Al) Metal-Organic Framework Upon Xenon Adsorption

被引：174

作者：

Boutin, Anne ^{[2
,4
]}

Springuel-Huet, Marie-Anne ^{[5
]}

Nossov, Andrei ^{[5
]}

Gedeon, Antoine ^{[5
]}

Loiseau, Thierry ^{[6
,7
]}

Volkringer, Christophe ^{[6
,7
]}

Ferey, Gerard ^{[6
,7
,8
]}

Coudert, Francois-Xavier ^{[1
,3
]}

Fuchs, Alain H. ^{[1
,3
]}

机构：

[1] Ecole Natl Super Chim Paris Chim ParisTech, CNRS, F-75005 Paris, France

[2] CNRS, Chim Phys Lab, F-91405 Orsay, France

[3] Univ Paris 06, F-75005 Paris, France

[4] Univ Paris 11, F-91405 Orsay, France

[5] Univ Paris 06, Lab Syst Interfaciaux Echelle Nanometr, F-75252 Paris 05, France

[6] CNRS, Inst Lavoisier, UMR 8180, F-78035 Versailles, France

[7] Univ Versailles, F-78035 Versailles, France

[8] Inst Univ France, Paris, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 44期

关键词：

adsorption; metal-organic frameworks; nanoporous materials; thermodynamics; xenon; HYDROCARBON ADSORPTION; COORDINATION POLYMERS; STRUCTURAL TRANSITION; SOLIDS; THERMODYNAMICS; DIFFRACTION; SIMULATIONS;

D O I：

10.1002/anie.200903153

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MOFs come alive: The combination of gas-adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature-loading phase diagram that displays unexpected re-entrant behavior. The breathing effect in the metal-organic framework MIL-53(AI) is predicted to be general and should be observed over a limited temperature range regardless of the guest adsorbate. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8314 / 8317

页数：4

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