Isolation and characterization of hydroformylation 'intermediates' from stoichiometric reactions between phosphinoalkenes and some heterobinuclear complexes

被引：23

作者：

Coutinho, KJ

Dickson, RS

Fallon, GD

Jackson, WR

DeSimone, T

Skelton, BW

White, AH

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a702922e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some heterobimetallic acyl and mu-acyl-rhodium complexes have been isolated from reactions of the phosphido-bridged complexes (OC)(4)M(mu-PPh2)(2)RhH(CO)(PPh3) with the phosphinoalkenes Ph2P(CH2)(n)CH=CH2 where M = Cr, Mo or W and n = 1-3. Several of the complexes have been fully characterized and their potential role as intermediates in the catalytic hydroformylation of the parent phosphines investigated and discussed.

引用

页码：3193 / 3199

页数：7

共 22 条

[1] ACYL GROUP FLIPPING IN HETERODIMETALLIC COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF [(ETA-5-C5H5)MOMN(MU-C(O)C6H11)(MU-PPH2)(CO)5] AND [(ETA-5-C5H5)MOMN(MU-C(O)-CH2CH2CH3)(MU-PPH2)(CO)6] [J].