Glass transition of dense fluids of hard and compressible spheres

We use computer simulations to study the glass transition of dense fluids made of polydisperse repulsive spheres. For hard particles, we vary the volume fraction, phi, and use compressible particles to explore finite temperatures, T>0. In the hard sphere limit, our dynamic data show evidence of an avoided mode-coupling singularity near phi(MCT)approximate to 0.592; they are consistent with a divergence of equilibrium relaxation times occurring at phi(0)approximate to 0.635, but they leave open the existence of a finite temperature singularity for compressible spheres at volume fraction phi>phi(0). Using direct measurements and a scaling procedure, we estimate the equilibrium equation of state for the hard sphere metastable fluid up to phi(0), where pressure remains finite, suggesting that phi(0) corresponds to an ideal glass transition. We use nonequilibrium protocols to explore glassy states above phi(0) and establish the existence of multiple equations of state for the unequilibrated glass of hard spheres, all diverging at different densities in the range phi is an element of[0.642,0.664]. Glassiness thus results in the existence of a continuum of densities where jamming transitions can occur.