Photo-activation of Pd-catalyzed Sonogashira coupling using a Ru/bipyridine complex as energy transfer agent

被引：122

作者：

Osawa, Masahisa ^{[1
]}

Nagai, Hidetada

Akita, Munetaka

机构：

[1] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

DALTON TRANSACTIONS | 2007年 / 08期

关键词：

COPPER-FREE; TERMINAL ALKYNES; ROOM-TEMPERATURE; VISIBLE-LIGHT; ARYL BROMIDES; POLYPYRIDINE COMPLEXES; AEROBIC CONDITIONS; EFFICIENT; WATER; ELECTROCHEMISTRY;

D O I：

10.1039/b618007h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed catalyst system, Pd(CH3CN)(2)Cl-2/P(t-Bu)(2)/[Ru(2, 2'-bipyridine)(3)](.)2PF(6), promotes the copper-free Sonogashira coupling reaction of aryl bromides at room temperature under irradiation of visible light.

引用

页码：827 / 829

页数：3

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