Poly(ferrocenylenevinylene) from ring-opening metathesis polymerization of ansa-(vinylene)ferrocene

被引：133

作者：

Buretea, MA

Tilley, TD

机构：

[1] UNIV CALIF BERKELEY, DEPT CHEM, BERKELEY, CA 94720 USA

[2] UNIV CALIF BERKELEY, LAWRENCE BERKELEY LAB, DIV CHEM SCI, BERKELEY, CA 94720 USA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 07期

关键词：

D O I：

10.1021/om960940l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The vinylene-bridged ansa-ferrocene complex [(eta(5)-C5H4)CH=CH(eta(5)-C5H4)]Fe (1) was synthesized by the McMurry coupling of 1,1'-ferrocenedicarbaldehyde (2). The ring opening metathesis polymerization (ROMP) of this strained metallocene gave poly(ferrocenylenevinylene) (3) as an insoluble orange solid which has a conductivity of 10(-3) Omega(-1) cm(-1) after doping with iodine. Partially soluble materials resulted when 1 was copolymerized with norbornene to yield a block copolymer.

引用

页码：1507 / 1510

页数：4

共 65 条

[1] WELL-DEFINED REDOX-ACTIVE POLYMERS AND BLOCK COPOLYMERS PREPARED BY LIVING RING-OPENING METATHESIS POLYMERIZATION [J].