Kinetic study on the oxidation of trichlorophenol using hydrogen peroxide and an iron(III) complex of tetrasulfonatophthalocyanine catalyst

被引：15

作者：

Kasuga, K ^{[1
]}

Mori, K ^{[1
]}

Sugimori, T ^{[1
]}

Handa, M ^{[1
]}

机构：

[1] Shimane Univ, Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2000年 / 73卷 / 04期

关键词：

D O I：

10.1246/bcsj.73.939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An oxidative decomposition of TCP, catalyzed by the title complex in the presence of hydrogen peroxide, was studied kinetically. The decrease in the initial reaction rate ill an acidic solution resulted from a depression of the proton dissociation of hydrogen peroxide.

引用

页码：939 / 940

页数：2

共 8 条

[1] OXIDATION OF PERSISTENT ENVIRONMENTAL-POLLUTANTS BY A WHITE ROT FUNGUS [J].

BUMPUS, JA ;

TIEN, M ;

WRIGHT, D ;

AUST, SD .

SCIENCE, 1985, 228 (4706) :1434-1436

[2] Sequential addition of H2O2, pH and solvent effects as key factors in the oxidation of 2,4,6-trichlorophenol catalyzed by iron tetrasulfophthalocyanine [J].

Hadasch, A ;

Sorokin, A ;

Rabion, A ;

Meunier, B .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (01) :45-51

[3]

HUYNH VB, 1985, TAPPI J, V68, P98

[4] Oxidation of pollutants catalyzed by metallophthalocyanines [J].

Meunier, B ;

Sorokin, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (11) :470-476

[5]

Sorokin A, 1998, EUR J INORG CHEM, P1269

[6] EFFICIENT OXIDATIVE DECHLORINATION AND AROMATIC RING-CLEAVAGE OF CHLORINATED PHENOLS CATALYZED BY IRON SULFOPHTHALOCYANINE [J].

SOROKIN, A ;

SERIS, JL ;

MEUNIER, B .

SCIENCE, 1995, 268 (5214) :1163-1166

[7] CO2 as the ultimate degradation product in the H2O2 oxidation of 2,4,6-trichlorophenol catalyzed by iron tetrasulfophthalocyanine [J].

Sorokin, A ;

DeSuzzoniDezard, S ;

Poullain, D ;

Noel, JP ;

Meunier, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (31) :7410-7411

[8] COMPLEXES DERIVED FROM STRONG FIELD LIGANDS .19. MAGNETIC PROPERTIES OF TRANSITION METAL DERIVATIVES OF 4,4',4'',4'''-TETRASULFOPHTHALOCYANINE [J].

WEBER, JH ;

BUSCH, DH .

INORGANIC CHEMISTRY, 1965, 4 (04) :469-&

← 1 →