Modification of the Surface Properties of Indium Tin Oxide with Benzylphosphonic Acids: A Joint Experimental and Theoretical Study

被引：151

作者：

Hotchkiss, Peter J. ^{[2
,3
]}

Li, Hong ^{[2
,3
]}

Paramonov, Pavel B. ^{[2
,3
]}

Paniagua, Sergio A. ^{[1
]}

Jones, Simon C. ^{[2
,3
]}

Armstrong, Neal R. ^{[1
]}

Bredas, Jean-Luc ^{[2
,3
]}

Marder, Seth R. ^{[2
,3
]}

机构：

[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA

[2] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

[3] Georgia Inst Technol, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 44期

基金：

美国国家科学基金会;

关键词：

SELF-ASSEMBLED MONOLAYERS; LIGHT-EMITTING-DIODES; RAY PHOTOELECTRON-SPECTROSCOPY; WORK FUNCTION; INTERFACE DIPOLES; CHARGE INJECTION; KELVIN PROBE; ITO; PHOTOEMISSION; PHOSPHONATES;

D O I：

10.1002/adma.200900502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

引用

页码：4496 / +

页数：7

共 71 条

[1] Interface dipoles arising from self-assembled monolayers on gold: UV-photoemission studies of alkanethiols and partially fluorinated alkanethiols [J].

Alloway, DM ;

Hofmann, M ;

Smith, DL ;

Gruhn, NE ;

Graham, AL ;

Colorado, R ;

Wysocki, VH ;

Lee, TR ;

Lee, PA ;

Armstrong, NR .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (42) :11690-11699

[2] Theoretical study of work function modification by organic molecule-derived linear nanostructure on H-silicon(100)-2 x 1 [J].

Anagaw, Arnsalu Y. ;

Wolkow, Robert A. ;

DiLabio, Gino A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (10) :3780-3784

[3] Organic electroluminescent devices: enhanced carrier injection using SAM derivatized ITO electrodes [J].

Appleyard, SFJ ;

Day, SR ;

Pickford, RD ;

Willis, MR .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (01) :169-173

[4] Interface modification of ITO thin films: organic photovoltaic cells [J].

Armstrong, NR ;

Carter, C ;

Donley, C ;

Simmonds, A ;

Lee, P ;

Brumbach, M ;

Kippelen, B ;

Domercq, B ;

Yoo, SY .

THIN SOLID FILMS, 2003, 445 (02) :342-352

[5] PROJECTOR AUGMENTED-WAVE METHOD [J].

BLOCHL, PE .

PHYSICAL REVIEW B, 1994, 50 (24) :17953-17979

[6] Influence of the electrode work function on the energy level alignment at organic-organic interfaces [J].

Braun, Slawomir ;

de Jong, Michel P. ;

Osikowicz, Wojciech ;

Salaneck, William R. .

APPLIED PHYSICS LETTERS, 2007, 91 (20)

[7] Formation of thiolate and phosphonate adlayers on indium-tin oxide: Optical and electronic characterization [J].

Brewer, SH ;

Brown, DA ;

Franzen, S .

LANGMUIR, 2002, 18 (18) :6857-6865

[8] Surface composition and electrical and electrochemical properties of freshly deposited and acid-etched indium tin oxide electrodes [J].

Brumbach, Michael ;

Veneman, P. Alex ;

Marrikar, F. Saneeha ;

Schulmeyer, Thomas ;

Simmonds, Adam ;

Xia, Wei ;

Lee, Paul ;

Armstrong, Neal R. .

LANGMUIR, 2007, 23 (22) :11089-11099

[9] Controlling the work function of indium tin oxide: Differentiating bipolar from local surface effects [J].

Bruner, EL ;

Koch, N ;

Span, AR ;

Bernasek, SL ;

Kahn, A ;

Schwartz, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (13) :3192-3193

[10] Electron energetics at surfaces and interfaces: Concepts and experiments [J].

Cahen, D ;

Kahn, A .

ADVANCED MATERIALS, 2003, 15 (04) :271-277

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