Plating of magnesium from organic solvents

被引：65

作者：

Lossius, LF ^{[1
]}

Emmenegger, F ^{[1
]}

机构：

[1] UNIV FRIBOURG,INST INORGAN CHEM,CH-1700 FRIBOURG,SWITZERLAND

来源：

ELECTROCHIMICA ACTA | 1996年 / 41卷 / 03期

关键词：

magnesium electrode; DMA; DMF;

D O I：

10.1016/0013-4686(95)00326-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In search of a reversible magnesium electrode at ambient temperature the solubilities, conductivities and reduction potentials of nine magnesium compounds, including MgCl2, MO(CF3SO3)(2) and Mg-acetylacetonate, were studied in 20 aprotic organic solvents (N- and O-donors) and 70 of their mixtures[1]. Although the goal was not reached, electrochemical dissolution and reduction of magnesium have been observed in systems with Mg(CF3SO3)(2) and the solvents dimethylformamide (DMF) dimethylacetamide (DMA) or gamma-Butyrolactone (gamma-BL).

引用

页码：445 / 447

页数：3

共 9 条

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