Synthesis of 2,3-dihydropyridines, cyclobutanopyrrolines and quinolines from lithiated allenes and isothiocyanates

被引：53

作者：

Brandsma, L

Nedolya, NA

Verkruijsse, HD

Owen, NL

Li, D

Trofimov, BA

机构：

[1] RUSSIAN ACAD SCI,INST ORGAN CHEM,IRKUTSK 664033,RUSSIA

[2] BRIGHAM YOUNG UNIV,DEPT CHEM & BIOCHEM,PROVO,UT 84602

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(97)01591-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The products obtained by S-alkylation of the adducts from lithiated allenes and alkyl or aryl isothiocyanates undergo thermal rearrangements with ultimate formation of derivatives of 2,3-dihydropyridine, cyclobutanopyrroline and quinoline, depending on the structure of the isothiocyanate. In some reactions azatrienes with a fully conjugated system can be isolated. (C) 1997 Elsevier Science Ltd.

引用

页码：6905 / 6908

页数：4