Synthesis of well-defined macromonomers by sequential ATRP-catalytic chain transfer and copolymerization with ethyl acrylate

被引：33

作者：

Norman, J

Moratti, SC

Slark, AT

Irvine, DJ

Jackson, AT

机构：

[1] Univ Cambridge, Dept Chem, Melville Polymer Lab, Cambridge CB2 1EW, England

[2] Natl Starch, Slough SL2 5DS, Berks, England

[3] Wilton Ctr, ICI Uniqema, Middlesbrough TS90 8JE, Cleveland, England

[4] ICI Technol, Middlesbrough TS90 8JE, Cleveland, England

来源：

MACROMOLECULES | 2002年 / 35卷 / 24期

关键词：

D O I：

10.1021/ma011011v

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymer chains with unsaturated end groups can be produced by the addition of catalytic chain transfer agents near the end of an atom-transfer polymerization. The polymers were analyzed by MALDI-TOF, NMR, and TGA experiments to determine the degree of unsaturation with good agreement. These polymers can subsequently be used as macromonomers in copolymerizations with monomers such as ethyl acrylate.

引用

收藏

页码：8954 / 8961

页数：8

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