From ceria nanotubes to nanowires through electrogeneration of base

被引：23

作者：

Bocchetta, P. ^{[1
]}

Santamaria, M. ^{[1
]}

Di Quarto, F. ^{[1
]}

机构：

[1] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, I-90129 Palermo, Italy

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2009年 / 39卷 / 11期

关键词：

Ceria; Nanowires; Nanotubes; Template; Electrogeneration of base; POROUS ANODIC ALUMINA; OXIDE FUEL-CELLS; CARBON-MONOXIDE OXIDATION; ELECTROCHEMICAL DEPOSITION; X-RAY; CEO2; RAMAN; FILMS; ELECTROSYNTHESIS; SCATTERING;

D O I：

10.1007/s10800-009-9866-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

070208 [无线电物理];

摘要：

The preparation of Ce(OH)(3)/CeO2 nanostructures (NSs) through electrogeneration of base into anodic alumina membranes was studied. The effects of solvent (alcohol and/or water), Ce3+ partner anion nature (chloride or nitrate) and concentration, applied potential or current density in driving the morphology toward nanowires (NWs) and/or nanotubes (NTs) was described. The structural analysis performed by X-Ray Diffraction and Raman Spectroscopy allowed to evidence that the presence of Ce(IV) into the nanostructures strongly depends on the oxygen content in the growing environment.

引用

收藏

页码：2073 / 2081

页数：9

相关论文

共 56 条

[1]

Studies of the formation of cerium-rich protective films using x-ray absorption near-edge spectroscopy and rotating disk electrode methods [J].

Aldykiewicz, AJ ;

Davenport, AJ ;

Isaacs, HS .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :147-154

[2]

BAO J, 2001, ADV MATER, V21, P13

[3]

Fabrication of cobalt nanostructures with different shapes in alumina template [J].

Bao, JC ;

Xu, Z ;

Hong, HM ;

Ma, X ;

Lu, ZH .

SCRIPTA MATERIALIA, 2004, 50 (01) :19-23

[4]

Nanoscale membrane electrode assemblies based on porous anodic alumina for hydrogen-oxygen fuel cell [J].

Bocchetta, P. ;

Conciauro, F. ;

Di Quarto, F. .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2007, 11 (09) :1253-1261

[5]

Template electrosynthesis of La(OH)3 and Nd(OH)3 nanowires using porous anodic alumina membranes [J].

Bocchetta, P. ;

Santamaria, M. ;

Di Quarto, F. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) :683-688

[6]

Nanoporous alumina membranes filled with solid acid for thin film fuel cells at intermediate temperatures [J].

Bocchetta, P ;

Chiavarotti, G ;

Masi, R ;

Sunseri, C ;

Di Quarto, F .

ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (09) :923-928

[7]

Electrosynthesis of Ce-Co mixed oxide nanotubes with high aspect ratio and tunable composition [J].

Bocchetta, Patrizia ;

Santamaria, Monica ;

Di Quarto, Francesco .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (03) :K27-K30

[8]

Cerium oxyhydroxide nanowire growth via electrogeneration of base in nonaqueous electrolytes [J].

Bocchetta, Patrizia ;

Santamaria, Monica ;

Di Quarto, Francesco .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (09) :K93-K97

[9]

Advances in anodic alumina membranes thin film fuel cell: CsH2PO4 pore-filler as proton conductor at room temperature [J].

Bocchetta, Patrizia ;

Ferraro, Rossella ;

Di Quarto, Francesco .

JOURNAL OF POWER SOURCES, 2009, 187 (01) :49-56

[10]

Kinetic and mechanistic studies of rare earth-rich protective film formation using in situ ellipsometry [J].

Böhm, S ;

Greef, R ;

McMurray, HN ;

Powell, SM ;

Worsley, DA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (09) :3286-3293

← 1 2 3 4 5 6 →