Ab initio evidence for slow fragmentation in RAFT polymerization

被引：133

作者：

Coote, ML ^{[1
]}

Radom, L ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 06期

关键词：

D O I：

10.1021/ja028645h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-level ab initio molecular orbital calculations on model reversible addition-fragmentation transfer (RAFT) polymerization reactions indicate that the retardation effect that is widely observed for methyl acrylate polymerization in the presence of cumyl dithiobenzoate may be attributed to the slow fragmentation of the RAFT adduct radical. Copyright © 2003 American Chemical Society.

引用

页码：1490 / 1491

页数：2

共 20 条

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