Benzoylperylenedicarboximides: Functional dyes with attractive optical and electronic properties

被引：14

作者：

Holtrup, FO ^{[1
]}

Muller, GRJ ^{[1
]}

Uebe, J ^{[1
]}

Mullen, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY

来源：

TETRAHEDRON | 1997年 / 53卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(97)00381-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Little is known about benzoylperleneimides 3. Two new syntheses of 3 have been worked out. based on boronic acid and organotin intermediates. respectively. These mild methods allow the isolation of the uncyclized precursor 10 and the introduction of various groups R. The purple benzoylperyleneimides 3 are fluorescent dyes and exhibit a high thermal and photochemical stability. The electrochemical properties have been investigated showing that 3 can take up 2 electrons while 10 accepts 4 electrons due to the existence of two weakly interacting anyl units. (C) 1997 Elsevier Science Ltd.

引用

页码：6847 / 6860

页数：14

共 29 条

[1] SYNTHESIS OF ORGANOTRIALKYLSTANNANES - THE REACTION BETWEEN ORGANIC HALIDES AND HEXAALKYLDISTANNANES IN THE PRESENCE OF PALLADIUM COMPLEXES [J].