Chemically tuned zero-field splittings and spin-lattice relaxation - Investigation by time-resolved emission

被引：18

作者：

Yersin, H

Strasser, J

机构：

[1] Inst. fur Phys. und Theor. Chem., Universität Regensburg

来源：

JOURNAL OF LUMINESCENCE | 1997年 / 72-4卷

关键词：

Ru(bpy)(3)](2+); Pt(II) compounds; zero-field splitting; spin-lattice relaxation;

D O I：

10.1016/S0022-2313(97)00014-8

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

For the compounds studied, zero-field splittings (zfs) of the lowest triplets lie between about 0.1 and 200 cm(-1). This energy determines spin-lattice relaxation (sir) rates and thus time developments of the emission. It is possible to shift these relaxation times into pre-defined time regions. The importance of these properties is demonstrated for the representative [Ru(bpy)(3)](2+).

引用

页码：462 / 463

页数：2

共 11 条

[1]

BALASHEV KP, UNPUB

[2]

DONGES D, 1997, L LUMIN, V72

[3] MAGNETICALLY PERTURBED, TEMPERATURE-DEPENDENT AND TIME-RESOLVED ASPECTS OF THE POLARIZED LUMINESCENCE OF RU(BPY) 2+3 BELOW 10-K [J].