Mesitylcopper: Tetrameric and pentameric

被引：100

作者：

Eriksson, H ^{[1
]}

Hakansson, M ^{[1
]}

机构：

[1] CHALMERS UNIV TECHNOL,DEPT INORGAN CHEM,S-41296 GOTHENBURG,SWEDEN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 20期

关键词：

D O I：

10.1021/om970462u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New phases containing tetrameric and pentameric mesitylcopper have been isolated from ether solvents and characterized with single-crystal X-ray diffraction. Mesitylcopper crystallized from toluene, which is a widely used reagent, has been found to contain one lattice solvent molecule. On the basis of these findings and cryoscopic molecular weight determinations, an equilibrium between a tetramer and pentamer in both etheral and aromatic solutions is proposed.

引用

页码：4243 / 4244

页数：2

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