Structural Modulation of Solid-State Emission of 2,5-Bis(trialkylsilylethynyl)-3,4-diphenylsiloles

被引：204

作者：

Zhao, Zujin ^{[1
]}

Wang, Zhiming ^{[2
]}

Lu, Ping ^{[1
]}

Chan, Carrie Y. K. ^{[1
]}

Liu, Dandan

Lam, Jacky W. Y. ^{[1
]}

Sung, Herman H. Y. ^{[1
]}

Williams, Ian D. ^{[1
]}

Ma, Yuguang ^{[2
]}

Tang, Ben Zhong ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

[2] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 41期

基金：

美国国家科学基金会;

关键词：

aggregation-induced emission; fluorescence; luminescence; siloles; structure-activity relationships; AGGREGATION-INDUCED EMISSION; LIGHT-EMISSION; SILOLE; PHOTOLUMINESCENCE; SUBSTITUENTS; MOLECULES; POLYMERS;

D O I：

10.1002/anie.200903698

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solidarity means strength: In new silole luminogens, the solid aggregates are stronger emitters than isolated molecules. The solid-state emission is tunable by varying molecular structures of the luminogens. Increasing bulkiness of the substituents weakens intermolecular interactions and restricts intramolecular rotations, leading to a blue shift in emission color and a great increase in emission efficiency (see examples in picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7608 / 7611

页数：4

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