Supramolecular chirality: A reporter of structural memory

被引：126

作者：

Ziegler, M ^{[1
]}

Davis, AV ^{[1
]}

Johnson, DW ^{[1
]}

Raymond, KN ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 06期

关键词：

chiral memory; circular dichroism; self-assembly; structural memory; supramolecular chemistry;

D O I：

10.1002/anie.200390183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Non-tetrahedron-forming L2 ligands insert into a resolved delta sign delta sign delta sign delta sign -[Ga4L16]12- tetrahedral assembly of labile metal and ligand components without compromising its supramolecular structure (see scheme). Preservation of the chirality of the initial architecture verifies its structural memory.

引用

页码：665 / 668

页数：4

共 23 条

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