Fabrication of Flexible Metal-Nanoparticte Film Using Graphene Oxide Sheets as Substrates

被引:312
作者
Xu, Chao [1 ]
Wang, Xin [1 ]
机构
[1] Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Minist Educ, Nanjing 210094, Peoples R China
基金
中国国家自然科学基金;
关键词
graphene; nanocomposites; particle films; reflectivity; surface-enhanced Raman scattering (SERS); SILVER MIRROR REACTION; GRAPHITE OXIDE; SURFACES; RAMAN; SERS; NANOCOMPOSITES; DISPERSIONS; NANOSHEETS; PAPER;
D O I
10.1002/smll.200900548
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene-based sheets that possess a unique nanostructure and a variety of fascinating properties are appealing as promising nanoscale building blocks of new composites. Herein, graphene oxide sheets are used as the nanoscale substrates for the formation of silver-nanoparticle films. These silver-nanoparticle films assembled on graphene oxide sheets are flexible and can form stable suspensions in aqueous solutions. They can also be easily processed, forming macroscopic films with high reflectivity. Raman signals of graphene oxide in such hybrid films are increased by the attached silver nanoparticles, displaying surface-enhanced Raman scattering activity. The degree of enhancement can be adjusted by varying the quantity of silver nanoparticles on the graphene oxide sheets.
引用
收藏
页码:2212 / 2217
页数:6
相关论文
共 42 条
[1]   Modeling of graphite oxide [J].
Boukhvalov, D. W. ;
Katsnelson, M. I. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10697-10701
[2]   Highly conductive carbon-nanotube/graphite-oxide hybrid films [J].
Cai, Dongyu ;
Song, Mo ;
Xu, Chenxi .
ADVANCED MATERIALS, 2008, 20 (09) :1706-+
[3]   Preparation and layer-by-layer self-assembly of silver nanoparticles capped by graphite oxide nanosheets [J].
Cassagneau, T ;
Fendler, JH .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (11) :1789-1793
[4]   Mechanically strong, electrically conductive, and biocompatible graphene paper [J].
Chen, Haiqun ;
Mueller, Marc B. ;
Gilmore, Kerry J. ;
Wallace, Gordon G. ;
Li, Dan .
ADVANCED MATERIALS, 2008, 20 (18) :3557-+
[5]   Single-walled carbon nanotube networks decorated with silver nanoparticles: A novel graded SERS substrate [J].
Chen, Yi-Chieh ;
Young, Robert J. ;
Macpherson, Julie V. ;
Wilson, Neil R. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (44) :16167-16173
[6]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[7]   Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].
Eda, Goki ;
Fanchini, Giovanni ;
Chhowalla, Manish .
NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274
[8]   One- and two-dimensional diffusion of metal atoms in graphene [J].
Gan, Yanjie ;
Sun, Litao ;
Banhart, Florian .
SMALL, 2008, 4 (05) :587-591
[9]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[10]   Intercalation and stitching of graphite oxide with diaminoalkanes [J].
Herrera-Alonso, Margarita ;
Abdala, Ahmed A. ;
McAllister, Michael J. ;
Aksay, Ilhan A. ;
Prud'homme, Robert K. .
LANGMUIR, 2007, 23 (21) :10644-10649