Block copolymers for photovoltaics

被引:220
作者
Darling, Seth B. [1 ]
机构
[1] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA
关键词
POLYMER SOLAR-CELLS; ACCEPTOR DIBLOCK COPOLYMERS; CONJUGATED POLYMERS; BAND-GAP; RADICAL POLYMERIZATION; ORGANIC SEMICONDUCTORS; SELF-ORGANIZATION; THIN-FILMS; BOTTOM-UP; DONOR;
D O I
10.1039/b912086f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photovoltaic energy conversion is arguably the most promising option for supplying renewable, carbon-neutral energy on a global scale. In order to reach grid parity, however, costs must be reduced substantially. Inexpensive materials generally exhibit efficiencies too low for practical application, but by controlling the morphology on the nanoscale there are opportunities to achieve significant improvements in this area. Block copolymers, which naturally self-assemble into periodic ordered nanostructures, can be utilized in diverse ways to control morphology, ranging from active layers to structure directors to a combination of these methodologies.
引用
收藏
页码:1266 / 1273
页数:8
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