Single crystals of the organic semiconductor perylene tetracarboxylic dianhydride studied by Raman spectroscopy

被引:70
作者
Tenne, DA [2 ]
Park, S
Kampen, TU
Das, A
Scholz, R
Zahn, DRT
机构
[1] Russian Acad Sci, Inst Semicond Phys, Novosibirsk 630090, Russia
[2] Tech Univ Chemnitz, Inst Phys, D-09107 Chemnitz, Germany
关键词
D O I
10.1103/PhysRevB.61.14564
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present Raman studies of the vibrational properties of 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) single crystals. Davydov splitting of internal molecular vibrations due to the interaction of two molecules in a unit cell was observed. Features of PTCDA crystal lattice vibrations in the low-frequency region of the Raman spectra are reported. PTCDA films deposited on passivated Si and GaAs surfaces also reveal the specific features of crystalline structure: Davydov splitting and appearance of phonon lines in Raman spectra.
引用
收藏
页码:14564 / 14569
页数:6
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