Nickel catalyzed electrosynthesis of ketones from organic halides and metal carbonyls.

被引：36

作者：

Dolhem, E ^{[1
]}

Ocafrain, M ^{[1
]}

Nedelec, JY ^{[1
]}

Troupel, M ^{[1
]}

机构：

[1] UNIV PARIS 12,CNRS,UMR 28,LAB ELECTROCHIM CATALYSE & SYNTH ORGAN,F-94320 THIAIS,FRANCE

来源：

TETRAHEDRON | 1997年 / 53卷 / 50期

关键词：

metal carbonyl; ketone electrosynthesis; nickel-2,2'-bipyridine catalysis;

D O I：

10.1016/S0040-4020(97)10143-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketones can be easily obtained by electroreduction in an undivided cell or an organic halide - metal carbonyl mixture using a Ni-bpy catalytic system in DMF (bpy = 2,2'-bipyridine). The process is especially well convenient Tor primary benzyl and alkyl halides. (C) 1997 Elsevier Science Ltd.

引用

页码：17089 / 17096

页数：8

共 24 条

[1] RATE AND MECHANISM OF THE REDUCTIONS OF IRON PENTACARBONYL AND CHROMIUM HEXACARBONYL TO THEIR METALATE COMPLEXES [J].

AMATORE, C ;

KRUSIC, PJ ;

PEDERSEN, SU ;

VERPEAUX, JN .

ORGANOMETALLICS, 1995, 14 (02) :640-649

[2] PALLADIUM-CATALYZED FORMYLATION OF ORGANIC HALIDES WITH CARBON-MONOXIDE AND TIN HYDRIDE [J].

BAILLARGEON, VP ;

STILLE, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :452-461

[3] FORMYLATION OF ARYL CHLORIDES CATALYZED BY A PALLADIUM COMPLEX [J].

BENDAVID, Y ;

PORTNOY, M ;

MILSTEIN, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) :1816-1817

[4] SYNTHESIS OF DIARYLKETONES THROUGH CARBONYLATIVE COUPLING [J].

BRUNET, JJ ;

CHAUVIN, R .

CHEMICAL SOCIETY REVIEWS, 1995, 24 (02) :89-95

[5] TETRACARBONYLHYDRIDOFERRATES, MHFE(CO)4 - VERSATILE TOOLS IN ORGANIC-SYNTHESIS AND CATALYSIS [J].

BRUNET, JJ .

CHEMICAL REVIEWS, 1990, 90 (06) :1041-1059

[6] Carbon Monoxide Insertion Reactions. I. The Carbonylation of Methyl Manganese Pentacarbonyl and Decarbonylation of Acetyl Manganese Pentacarbonyl [J].

Calderazzo, Faust ;

Cotton, F. Albert .

INORGANIC CHEMISTRY, 1962, 1 (01) :30-36

[7]

CHAUSSARD J, 1990, SYNTHESIS-STUTTGART, P369

[8] LEWIS ACID-CATALYZED [RFE(CO)4]- ALKYL MIGRATION REACTIONS - MECHANISTIC INVESTIGATION [J].

COLLMAN, JP ;

FINKE, RG ;

CAWSE, JN ;

BRAUMAN, JI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (15) :4766-4772

[9]

COLLMAN JP, 1975, ACCOUNTS CHEM RES, V8, P242

[10]

Colquhoun H.M., 1991, Carbonylation, Direct Synthesis of Carbonyl Compounds

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