Crystal structure of the molecular addition compound diphenylchloroborane•tetrahydrofuran

被引:12
作者
Cross, WI [1 ]
Lightfoot, MP [1 ]
Mair, FS [1 ]
Pritchard, RG [1 ]
机构
[1] Univ Manchester, Dept Chem, Manchester M60 1QD, Lancs, England
关键词
D O I
10.1021/ic991148q
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Crystalline Ph2BCl·O(CH2)4 is an unexpectedly stable complex containing an intact THF ligand in the presence of a boron halide bond. The short B-O and long B-Cl bonds of this ether cleavage precursor complex are rationalized using Gillespie's ligand close-packing arguments.
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页码:2690 / +
页数:4
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