Crystal structure of the molecular addition compound diphenylchloroborane•tetrahydrofuran

被引：12

作者：

Cross, WI ^{[1
]}

Lightfoot, MP ^{[1
]}

Mair, FS ^{[1
]}

Pritchard, RG ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M60 1QD, Lancs, England

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 12期

关键词：

D O I：

10.1021/ic991148q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystalline Ph2BCl·O(CH2)4 is an unexpectedly stable complex containing an intact THF ligand in the presence of a boron halide bond. The short B-O and long B-Cl bonds of this ether cleavage precursor complex are rationalized using Gillespie's ligand close-packing arguments.

引用

页码：2690 / +

页数：4

共 18 条

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