Synthesis and characterisation of the methanofullerenes, C-60(CHCN) and C-60(CBr2)

被引：34

作者：

Benito, AM

Darwish, AD

Kroto, HW

Meidine, MF

Taylor, R

Walton, DRM

机构：

[1] Sch. of Chem. and Molecular Sciences, University of Sussex

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0040-4039(95)02256-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new methanofullerenes, C-60(CHCN) and C-60(CBr2), have been prepared by treating a mixture of [60]fullerene and either CH2BrCN or CHBr3 respectively with LDA. The products were purified by silica gel column chromatography, characterised by EI-MS and IR and shown by C-13 NMR to consist solely of 6-6 ring junction adducts.

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页码：1085 / 1086

页数：2

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