学术探索
学术期刊
新闻热点
数据分析
智能评审

Structure elucidation of the photoproducts obtained by the photolysis of N-acetyl-2-styrylpyrroles

被引：9
作者：
Basaric, N
Ivekovic, D
Zimmermann, B
Marinic, E
Kowski, K
Rademacher, P
Sindler-Kulyk, M
机构：
[1] Univ Zagreb, Dept Organ Chem, Fac Chem Engn & Technol, HR-10000 Zagreb, Croatia
[2] Univ Zagreb, Dept Inorgan Chem, Fac Biochem Engn & Food Technol, HR-10000 Zagreb, Croatia
[3] Rudjer Boskovic Inst, NMR Ctr, HR-10002 Zagreb, Croatia
[4] Univ Essen Gesamthsch, Inst Organ Chem, D-45117 Essen, Germany
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2003年 / 154卷 / 2-3期
关键词：
pyrroles; photochemistry; phototransposition; photolysis; oxidation potentials; electron transfer; acetylation;
D O I：
10.1016/S1010-6030(02)00352-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
From the irradiation mixture of N-acetyl-2-styrylpyrroles (5a, b) the deacylated (6a, b), phototransposition (7a, b-10a, b), electrocyclisation (12), addition and reduction (11, 13 and 14) and dimerisation products (15) have been detected. No intramolecular cycloaddition products have been observed. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：123 / 130
页数：8
相关论文
共 33 条
[1]  
Austin M, 1997, LIEBIGS ANN-RECL, P943
[2]   New photoinduced intramolecular ring closure to a benzopentaleno-pyrrole derivative from 5,5′-dimethyl-2,2′-(o-phenylenedivinylene)dipyrrole [J].
Basaric, N ;
Marinic, Z ;
Sindler-Kulyk, M .
TETRAHEDRON LETTERS, 2001, 42 (21) :3641-3643
[3]   Photochemical formation of indanylpyrrole derivatives from 2,2′-(o-phenylenedivinylene)dipyrrole [J].
Basaric, N ;
Tomsic, S ;
Marinic, Z ;
Sindler-Kulyk, M .
TETRAHEDRON, 2000, 56 (11) :1587-1593
[4]   1,4-PHOTOADDITION OF PYRROLE TO BENZENE [J].
BELLAS, M ;
BRYCESMI.D ;
GILBERT, A .
CHEMICAL COMMUNICATIONS, 1967, (06) :263-&
[5]   NMR STEREOSPECIFIC LONG-RANGE COUPLING AND PREFERRED CONFORMATIONS IN SOME (E)- AND (Z)-ALPHA-PHENYL-BETA-[2-(N-METHYL)NITROPYRROLYL] ACRYLIC ACIDS [J].
BOTTINO, FA ;
MINERI, G ;
SCIOTTO, D .
TETRAHEDRON, 1978, 34 (10) :1557-1559
[6]   ORGANIC-PHOTOCHEMISTRY OF BENZENE .2. [J].
BRYCESMITH, D ;
GILBERT, A .
TETRAHEDRON, 1977, 33 (19) :2459-2490
[7]  
BRYCESMITH D, 1971, CHEM COMMUN, P916
[8]   Structure elucidation and assignment of 1H and 13C spectra of the new fused cyclobutane-naphthofuran derivative by two-dimensional NMR in different solvents [J].
Cvijin, IV ;
Marinic, Z ;
Sindler-Kulyk, M .
SPECTROSCOPY LETTERS, 1998, 31 (05) :989-1000
[9]   THE MECHANISM OF THE PHOTOCHEMICAL CYCLOADDITION REACTION OF N-BENZOYLINDOLE WITH CYCLOPENTENE [J].
DISANAYAKA, BW ;
WEEDON, AC .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1990, 68 (10) :1685-1692
[10]   UNEXPECTED LACK OF STEREOSELECTIVITY IN THE HORNER-WADSWORTH-EMMONS REACTION WHEN APPLIED TO THE SYNTHESIS OF (E)- AND (Z)-METHYL A-ARYLCINNAMATES [J].
GEIRSSON, JKF ;
GUDMUNDSSON, BO ;
SIGURDARDOTTIR, R .
ACTA CHEMICA SCANDINAVICA, 1993, 47 (11) :1112-1116
1234