The synthesis of sultines from delta-hydroxy sulfoxides revisited

被引：10

作者：

Connolly, TJ

Durst, T

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(97)00093-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A re-examination of a previously thought general synthesis of sultines from delta-hydroxy sulfoxides is shown to be more complicated than originally believed. The products obtained can be alpha,alpha'-dihaloxylenes or delta-halosulfones. The results are best interpreted based on carbocation stability of the key oxo-sulfoxonium salt intermediate. (C) 1997 Elsevier Science Ltd.

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页码：1337 / 1340

页数：4

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