A short, efficient synthesis of the chiral auxiliary (+)-8-phenylneomenthol

被引：14

作者：

Caamaño, O ^{[1
]}

Fernández, F ^{[1
]}

García-Mera, X ^{[1
]}

Rodríguez-Borges, JE ^{[1
]}

机构：

[1] Univ Santiago, Fac Farm, Dept Quim Organ, E-15706 Santiago, Spain

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 21期

关键词：

terpene alcohols; chiral auxiliaries; phenylneomenthol; Sarett oxidation; L-Selectride;

D O I：

10.1016/S0040-4039(00)00594-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+)-8-Phenylneomenthol 2, the structure of which was confirmed by X-ray analysis of its 3,5-dinitrobenzoate, was efficiently prepared from commercially available (-)-8-phenylmenthol 3 by oxidation with the Sarett reagent, followed by L-Selectride reduction of the (+)-8-phenylmenthone 6 thus formed. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4123 / 4125

页数：3

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