All solid-state lithium secondary batteries using high lithium ion conducting Li2S-P2S5 glass-ceramics

被引:77
作者
Mizuno, F [1 ]
Hama, S [1 ]
Hayashi, A [1 ]
Tadanaga, K [1 ]
Minami, T [1 ]
Tatsumisago, M [1 ]
机构
[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Mat Sci, Sakai, Osaka 5998531, Japan
关键词
D O I
10.1246/cl.2002.1244
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
All solid-state cells of In/LiCoO2 using the 80Li(2)S(.)20P(2)S(5) (mol%) glass-ceramics with high ambient temperature conductivity of about 10(-3) S cm(-1) as a solid electrolyte were fabricated, and the cell performance was investigated. Although an irreversible capacity was observed at the 1st cycle, the solid-state cell exhibited excellent cycling performances with the reversible charge-discharge capacities of about 100 mAh g(-1) even after 200 cycles.
引用
收藏
页码:1244 / 1245
页数:2
相关论文
共 12 条
[1]   Characterization of Li2S-SiS2-LixMOy (M=Si, P, Ge) amorphous solid electrolytes prepared by melt-quenching and mechanical milling [J].
Hayashi, A ;
Yamashita, H ;
Tatsumisago, M ;
Minami, T .
SOLID STATE IONICS, 2002, 148 (3-4) :381-389
[2]  
Hayashi A, 2001, J AM CERAM SOC, V84, P477, DOI 10.1111/j.1151-2916.2001.tb00685.x
[3]   High lithium ion conductivity of glass-ceramics derived from mechanically milled glassy powders [J].
Hayashi, A ;
Hama, S ;
Morimoto, H ;
Tatsumisago, M ;
Minami, T .
CHEMISTRY LETTERS, 2001, (09) :872-873
[4]  
HAYASHI A, UNPUB J MAT CHEM
[5]   Lithium ionic conductor thio-LISICON -: The Li2S-GeS2-P2S5 system [J].
Kanno, R ;
Maruyama, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (07) :A742-A746
[6]   IONICALLY CONDUCTIVE GLASSES BASED ON SIS2 [J].
KENNEDY, JH .
MATERIALS CHEMISTRY AND PHYSICS, 1989, 23 (1-2) :29-50
[7]   Solid state lithium secondary batteries using an amorphous solid electrolyte in the system (100-x)(0.6Li2S • 0.4SiS2) • xLi4SiO4 obtained by mechanochemical synthesis [J].
Komiya, R ;
Hayashi, A ;
Morimoto, H ;
Tatsumisago, M ;
Minami, T .
SOLID STATE IONICS, 2001, 140 (1-2) :83-87
[8]   SUPERIONIC CONDUCTION IN LI2S-P2S5-LII-GLASSES [J].
MERCIER, R ;
MALUGANI, JP ;
FAHYS, B ;
ROBERT, G .
SOLID STATE IONICS, 1981, 5 (OCT) :663-666
[9]   Preparation and characterization of lithium ion-conducting oxysulfide glasses [J].
Minami, T ;
Hayashi, A ;
Tatsumisago, M .
SOLID STATE IONICS, 2000, 136 :1015-1023
[10]  
Morimoto H, 1999, J AM CERAM SOC, V82, P1352, DOI 10.1111/j.1151-2916.1999.tb01923.x