Water-soluble poly(4,7,10,13-tetraoxatetradecylmethylsilane): Enhanced yield and improved purity via polymerization using graphite-potassium (C8K) as reducing agent

被引：15

作者：

Cleij, TJ ^{[1
]}

Tsang, SKY ^{[1
]}

Jenneskens, LW ^{[1
]}

机构：

[1] UNIV UTRECHT,DEPT PHYS ORGAN CHEM,DEBYE INST,NL-3584 CH UTRECHT,NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 03期

关键词：

D O I：

10.1039/a607786b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Application of graphite-potassium (C8K, THF, 0 degrees C), instead of convential Wurtz-type coupling conditions (Na, toluene, 110 degrees C), as reducing agent for the preparation of non-ionic, watersoluble poly(4,7,10,13-tetraoxatetradecylmethylsilane) 1 gives a markedly enhanced yield as well as a high molecular weight polymer of high purity.

引用

页码：329 / 330

页数：2

共 22 条

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