Array membrane electrode assemblies for high throughput screening of direct methanol fuel cell anode catalysts

被引:85
作者
Liu, RX
Smotkin, ES
机构
[1] NuVant Syst, Chicago, IL 60616 USA
[2] Univ Puerto Rico, Dept Chem, Rio Piedras, PR 00931 USA
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2002年 / 535卷 / 1-2期
关键词
array fuel cell; membrane electrode assemblies;
D O I
10.1016/S0022-0728(02)01144-0
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A fuel cell using an array membrane electrode assembly has been developed for the high throughput screening of fuel cell electrocatalysts. Standard membrane and electrode assembly methods are used. The use of modified fuel cell hardware permits the use of realistic catalyst exposure histories and steady state reaction conditions. The array fuel cell requires no supplemental electrolytes. The performance of the array fuel cell is demonstrated by the testing of one prepared in-house and three commercially available fuel cell catalysts. Within the potential range of a DMFC anode (i.e. 0.3-0.4 V), the catalyst rankings were PtRu (Johnson Matthey) > PtRu oxide (E-Tek) > PtRu (reduced by NaBH4) > Pt. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:49 / 55
页数:7
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