In Situ Synthesis of an Imidazolate-4-amide-5-imidate Ligand and Formation of a Microporous Zinc-Organic Framework with H2-and CO2-Storage Ability

被引：123

作者：

Debatin, Franziska ^{[1
]}

Thomas, Arne ^{[2
]}

Kelling, Alexandra ^{[1
]}

Hedin, Niklas ^{[3
]}

Bacsik, Zoltan ^{[3
]}

Senkovska, Irena ^{[4
]}

Kaskel, Stefan ^{[4
]}

Junginger, Matthias ^{[1
]}

Mueller, Holger ^{[1
]}

Schilde, Uwe ^{[1
]}

Jaeger, Christian ^{[5
]}

Friedrich, Alwin ^{[1
]}

Holdt, Hans-Juergen ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, D-14476 Golm, Germany

[2] Tech Univ Berlin, Inst Chem, Fak 2, D-10623 Berlin, Germany

[3] Stockholm Univ, Dept Phys Inorgan & Struct Chem, Arrhenius Lab, S-10691 Stockholm, Sweden

[4] Tech Univ Dresden, D-01062 Dresden, Germany

[5] Fed Inst Mat Res & Testing, BAM, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 07期

关键词：

gas sorption; metal-organic frameworks; microporous materials; N; O ligands; solvothermal synthesis; ZEOLITIC IMIDAZOLATE FRAMEWORKS; POROUS COORDINATION POLYMERS; ION-EXCHANGE PROPERTIES; HYDROGEN STORAGE; MAGNETIC-PROPERTIES; BUILDING-BLOCKS; CRYSTAL-STRUCTURES; METAL; ADSORPTION; IMIDAZOLE-4,5-DICARBOXYLATE;

D O I：

10.1002/anie.200906188

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"(Figure Presented)" Narrow channels with polar walls are the structural and functional features responsible for the high capacity of a zinc-organic framework based on an imidazolate-amide-imidate ligand for the uptake of H2 and CO2 (see structure: orange Zn, blue N, red O, dark gray C, light gray H). The rigid and stable chelating ligand was synthesized in situ by partial hydrolysis of a dicyanoimidazole compound. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA,.

引用

页码：1258 / 1262

页数：5

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