共 22 条
Easy synthesis of an ordered mesoporous carbon with a hexagonally packed tubular structure
被引:160
作者:

Lu, AH
论文数: 0 引用数: 0
h-index: 0
机构: Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany

Li, WC
论文数: 0 引用数: 0
h-index: 0
机构: Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany

Schmidt, W
论文数: 0 引用数: 0
h-index: 0
机构: Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany

Kiefer, W
论文数: 0 引用数: 0
h-index: 0
机构: Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany

Schüth, F
论文数: 0 引用数: 0
h-index: 0
机构: Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany
机构:
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany
[2] Univ Wurzburg, Inst Phys Chem, D-97074 Wurzburg, Germany
来源:
关键词:
porous carbon;
impregnation;
pyrolysis;
adsorption;
X-ray diffraction;
D O I:
10.1016/j.carbon.2004.07.006
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Ordered mesoporous carbon with hexagonal arrays of tubes (CMK-5) was successfully synthesized via a nanocasting process by directly using SBA-15; instead of AlSBA-15, as a template, furfuryl alcohol as a carbon source and oxalic acid as the catalyst. The time consuming impregnation of SBA-15 with aluminum could be saved. The as-synthesized CMK-5 exhibits a tubular structure with double pore system. The loading amount of carbon precursor on the pore walls of SBA-15 is the key factor for the formation of the CMK-5 structure with two-dimensional hexagonal arrays of tubes, and the pore diameter can be adjusted by varying the loading amount of the carbon precursor. The CMK-5 carbon exhibits high apparent surface area up to similar to2500 m(2)/g and high pore volume reaching similar to2 cm(3)/g, which is due to the unique structure of CMK-5. The characterization results confirmed that carbonization under argon atmosphere instead of vacuum is sufficient for the structural formation of CMK-5 carbons, and can be used as an alternative pathway to prepare tubular-type carbons. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2939 / 2948
页数:10
相关论文
共 22 条
[1]
Direct observation of 3D mesoporous structure by scanning electron microscopy (SEM): SBA-15 silica and CMK-5 carbon
[J].
Che, SN
;
Lund, K
;
Tatsumi, T
;
Iijima, S
;
Joo, SH
;
Ryoo, R
;
Terasaki, O
.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,
2003, 42 (19)
:2182-2185

Che, SN
论文数: 0 引用数: 0
h-index: 0
机构: Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan

Lund, K
论文数: 0 引用数: 0
h-index: 0
机构: Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan

Tatsumi, T
论文数: 0 引用数: 0
h-index: 0
机构: Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan

Iijima, S
论文数: 0 引用数: 0
h-index: 0
机构: Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan

Joo, SH
论文数: 0 引用数: 0
h-index: 0
机构: Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan

Ryoo, R
论文数: 0 引用数: 0
h-index: 0
机构: Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan

Terasaki, O
论文数: 0 引用数: 0
h-index: 0
机构:
Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan
[2]
Double-walled carbon nanotubes fabricated by a hydrogen arc discharge method
[J].
Hutchison, JL
;
Kiselev, NA
;
Krinichnaya, EP
;
Krestinin, AV
;
Loutfy, RO
;
Morawsky, AP
;
Muradyan, VE
;
Obraztsova, ED
;
Sloan, J
;
Terekhov, SV
;
Zakharov, DN
.
CARBON,
2001, 39 (05)
:761-770

Hutchison, JL
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Kiselev, NA
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Krinichnaya, EP
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Krestinin, AV
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Loutfy, RO
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Morawsky, AP
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Muradyan, VE
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Obraztsova, ED
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Sloan, J
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Terekhov, SV
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia

Zakharov, DN
论文数: 0 引用数: 0
h-index: 0
机构: Russian Acad Sci, Inst Crystallog, Moscow 117333, Russia
[3]
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles
[J].
Joo, SH
;
Choi, SJ
;
Oh, I
;
Kwak, J
;
Liu, Z
;
Terasaki, O
;
Ryoo, R
.
NATURE,
2001, 412 (6843)
:169-172

Joo, SH
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea

Choi, SJ
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea

Oh, I
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea

Kwak, J
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea

Liu, Z
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea

Terasaki, O
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea

Ryoo, R
论文数: 0 引用数: 0
h-index: 0
机构:
Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea Korea Adv Inst Sci & Technol, Natl Craet Res Initiat Ctr Funct Nanomat, Taejon 305701, South Korea
[4]
Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure
[J].
Jun, S
;
Joo, SH
;
Ryoo, R
;
Kruk, M
;
Jaroniec, M
;
Liu, Z
;
Ohsuna, T
;
Terasaki, O
.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
2000, 122 (43)
:10712-10713

Jun, S
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

Joo, SH
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

Ryoo, R
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

Kruk, M
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

Jaroniec, M
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

Liu, Z
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

Ohsuna, T
论文数: 0 引用数: 0
h-index: 0
机构: Korea Adv Inst Sci & Technol, Sch Mol Sci, Mat Chem Lab, Taejon 305701, South Korea

论文数: 引用数:
h-index:
机构:
[5]
One-step water-assisted synthesis of high-quality carbon nanotubes directly from graphite
[J].
Kang, ZH
;
Wang, EB
;
Gao, L
;
Lian, SY
;
Jiang, M
;
Hu, CW
;
Xu, L
.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
2003, 125 (45)
:13652-13653

Kang, ZH
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

Wang, EB
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

Gao, L
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

Lian, SY
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

Jiang, M
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

Hu, CW
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

Xu, L
论文数: 0 引用数: 0
h-index: 0
机构:
NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China
[6]
Cubic Ia3d large mesoporous silica:: synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes
[J].
Kleitz, F
;
Choi, SH
;
Ryoo, R
.
CHEMICAL COMMUNICATIONS,
2003, (17)
:2136-2137

Kleitz, F
论文数: 0 引用数: 0
h-index: 0
机构:
Korea Adv Inst Sci & Technol, Dept Chem, Natl Creat Res Initiat Ctr Funct Nanomat, Sch Mol Sci, Taejon 305701, South Korea Korea Adv Inst Sci & Technol, Dept Chem, Natl Creat Res Initiat Ctr Funct Nanomat, Sch Mol Sci, Taejon 305701, South Korea

Choi, SH
论文数: 0 引用数: 0
h-index: 0
机构:
Korea Adv Inst Sci & Technol, Dept Chem, Natl Creat Res Initiat Ctr Funct Nanomat, Sch Mol Sci, Taejon 305701, South Korea Korea Adv Inst Sci & Technol, Dept Chem, Natl Creat Res Initiat Ctr Funct Nanomat, Sch Mol Sci, Taejon 305701, South Korea

Ryoo, R
论文数: 0 引用数: 0
h-index: 0
机构:
Korea Adv Inst Sci & Technol, Dept Chem, Natl Creat Res Initiat Ctr Funct Nanomat, Sch Mol Sci, Taejon 305701, South Korea Korea Adv Inst Sci & Technol, Dept Chem, Natl Creat Res Initiat Ctr Funct Nanomat, Sch Mol Sci, Taejon 305701, South Korea
[7]
Synthesis and characterization of hexagonally ordered carbon nanopipes
[J].
Kruk, M
;
Jaroniec, M
;
Kim, TW
;
Ryoo, R
.
CHEMISTRY OF MATERIALS,
2003, 15 (14)
:2815-2823

Kruk, M
论文数: 0 引用数: 0
h-index: 0
机构: Kent State Univ, Dept Chem, Kent, OH 44242 USA

Jaroniec, M
论文数: 0 引用数: 0
h-index: 0
机构:
Kent State Univ, Dept Chem, Kent, OH 44242 USA Kent State Univ, Dept Chem, Kent, OH 44242 USA

Kim, TW
论文数: 0 引用数: 0
h-index: 0
机构: Kent State Univ, Dept Chem, Kent, OH 44242 USA

Ryoo, R
论文数: 0 引用数: 0
h-index: 0
机构: Kent State Univ, Dept Chem, Kent, OH 44242 USA
[8]
Control of pore structure in carbon
[J].
Kyotani, T
.
CARBON,
2000, 38 (02)
:269-286

Kyotani, T
论文数: 0 引用数: 0
h-index: 0
机构:
Tohoku Univ, Inst Chem React Sci, Sendai, Miyagi 9808577, Japan Tohoku Univ, Inst Chem React Sci, Sendai, Miyagi 9808577, Japan
[9]
Performance of CoMoS catalysts supported on nanoporous carbon in the hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene
[J].
Lee, JJ
;
Han, S
;
Kim, H
;
Koh, JH
;
Hyeon, T
;
Moon, SH
.
CATALYSIS TODAY,
2003, 86 (1-4)
:141-149

Lee, JJ
论文数: 0 引用数: 0
h-index: 0
机构: Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea

Han, S
论文数: 0 引用数: 0
h-index: 0
机构: Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea

Kim, H
论文数: 0 引用数: 0
h-index: 0
机构: Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea

Koh, JH
论文数: 0 引用数: 0
h-index: 0
机构: Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea

Hyeon, T
论文数: 0 引用数: 0
h-index: 0
机构: Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea

Moon, SH
论文数: 0 引用数: 0
h-index: 0
机构: Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea
[10]
Synthesis of ordered mesoporous carbon with bimodal pore system and high pore volume
[J].
Lu, AH
;
Schmidt, W
;
Spliethoff, B
;
Schüth, F
.
ADVANCED MATERIALS,
2003, 15 (19)
:1602-+

Lu, AH
论文数: 0 引用数: 0
h-index: 0
机构:
Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

Schmidt, W
论文数: 0 引用数: 0
h-index: 0
机构:
Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

Spliethoff, B
论文数: 0 引用数: 0
h-index: 0
机构:
Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

Schüth, F
论文数: 0 引用数: 0
h-index: 0
机构:
Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany