Hydrogen generation from biogas reforming using a gliding arc plasma-catalyst reformer

被引:63
作者
Chun, Young. N. [1 ]
Yang, Yoon C. [1 ]
Yoshikawa, K. [2 ]
机构
[1] Chosun Univ, Dept Environm Engn, Team Hydrogen Prod BK21, Kwangju 501759, South Korea
[2] Tokyo Inst Technol, Frontier Res Ctr, Midori Ku, Yokohama, Kanagawa 2268502, Japan
关键词
Gliding arc plasma; Ni catalyst; Hydrogen generation; Biogas; Reforming; NONTHERMAL PLASMA; GAS-PRODUCTION; METHANE; DISCHARGE; REMOVAL; SYSTEM;
D O I
10.1016/j.cattod.2009.09.019
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Biogas generated from landfills, wastewater disposal plants, wastes of livestock houses, etc., causing global warming when released into the air. This study developed a GAPCR (Gliding Arc Plasma-Catalyst Reformer) which convert the biogas into higher percentage of hydrogen as low pollution recycling energy, reduced the global warming and environmental problems. This study also conducted tests for the different variables that affect the biogas reforming efficiency of the GAPCR, and presented the optimum operating conditions for high percentage of hydrogen generation. The parametric studies were carried out according to the change of steam to carbon ratio, catalyst bed temperature, total gas flow rate, input electric power, and biogas component ratio, i.e., CH(4):CO(2). The hydrogen concentration increased up to specific limit, and then maintained almost constant values for the same steam to carbon ratio and catalyst bed temperature. Hydrogen percentage decreased with the increase in total gas flow rate but little bit increases with the increase in electric power. In terms of biogas component ratio, hydrogen concentration decreased with the increase of CO(2) amount. The optimum operating conditions showed the concentrations of 62% H(2), 8% CO, 27% CO(2), and 0.0% CH(4) on the basis of steam to carbon ratio of 3, catalyst bed temperature of 700 degrees C, total gas flow rate of 16 L/min, input electric power of 2.4 kW, and biogas component ratio of 6:4 (CH(4):CO(2)). At this condition. H(2) yield and H(2) selectivity were same values of 59%. Energy efficiency and specific energy requirement were 53% and 289 kJ/mol, respectively. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:283 / 289
页数:7
相关论文
共 19 条
[1]   Organic dye removal from aqueous solution by glidarc discharges [J].
Burlica, R ;
Kirkpatrick, MJ ;
Finney, WC ;
Clark, RJ ;
Locke, BR .
JOURNAL OF ELECTROSTATICS, 2004, 62 (04) :309-321
[2]   Syngas production using gliding arc plasma [J].
Chun, Y. N. ;
Song, H. O. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2008, 30 (13) :1202-1212
[3]   Production of hydrogen-rich gas from methane by thermal plasma reform [J].
Chun, Young N. ;
Kim, Seong C. .
JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION, 2007, 57 (12) :1447-1451
[4]   Methane steam reforming and ethanol steam reforming using a Ni(II)-Al(III) catalyst prepared from lamellar double hydroxides [J].
Comas, J ;
Dieuzeide, ML ;
Baronetti, G ;
Laborde, M ;
Amadeo, N .
CHEMICAL ENGINEERING JOURNAL, 2006, 118 (1-2) :11-15
[5]   Simultaneous removal of polycyclic aromatic hydrocarbons and soot particles from flue gas by gliding arc discharge treatment [J].
Du, Ch. M. ;
Yan, J. H. ;
Li, X. D. ;
Cheron, B. G. ;
You, X. F. ;
Chi, Y. ;
Ni, M. J. ;
Cen, K. F. .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2006, 26 (05) :517-525
[6]   THE CHEMISTRY OF METHANE REFORMING WITH CARBON-DIOXIDE AND ITS CURRENT AND POTENTIAL APPLICATIONS [J].
EDWARDS, JH ;
MAITRA, AM .
FUEL PROCESSING TECHNOLOGY, 1995, 42 (2-3) :269-289
[7]   Gliding arc gas discharge [J].
Fridman, A ;
Nester, S ;
Kennedy, LA ;
Saveliev, A ;
Mutaf-Yardimci, O .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 1999, 25 (02) :211-231
[8]  
Indarto A, 2006, ENERGY, V31, P2986, DOI 10.1016/j.energy.2005.10.034
[9]   Hydrogen generation from water, methane, and methanol with nonthermal plasma [J].
Kabashima, H ;
Einaga, H ;
Futamura, S .
IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, 2003, 39 (02) :340-345
[10]   Catalytic steam reforming of model biogas [J].
Kolbitsch, Philipp ;
Pfeifer, Christoph ;
Hofbauer, Hermann .
FUEL, 2008, 87 (06) :701-706