Practical performances of Li-ion polymer batteries with LiNi0.8Co0.2O2, MCMB, and PAN-based gel electrolyte

被引：30

作者：

Akashi, H ^{[1
]}

Shibuya, M ^{[1
]}

Orui, K ^{[1
]}

Shibamoto, G ^{[1
]}

Sekai, K ^{[1
]}

机构：

[1] Sony Corp, Yokohama Res Ctr, Hodogaya Ku, Yokohama, Kanagawa 2400036, Japan

来源：

JOURNAL OF POWER SOURCES | 2002年 / 112卷 / 02期

关键词：

Li-ion polymer battery; gel electrolyte; poly(acrylonitrile); thermal stability; lithium nickel dioxide; mesocarbon microbeads;

D O I：

10.1016/S0378-7753(02)00465-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The practical performances and thermal stability of Li-ion polymer batteries with LiNi0.8Co0.2O2, mesocarbon microbead-based graphite, and poly(acrylonitrile) (PAN)-based gel electrolytes are reported. The gel electrolyte, which shows a fire-retardance by itself as well as good chemical stability effectively improved thermal stability of the Li-ion polymer battery up to 170 degreesC. We also found that the mesocarbon microbead-based graphite showed better coulombic efficiency even though the gel electrolyte contained PC and GBL. An evaluation of cell performances showed that the electrodes and the gel electrolyte were promising material for a next-generation Li-ion polymer battery. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：577 / 582

页数：6

共 42 条

[1] A comparative study of coordination in gel electrolytes -: Quantitative analysis
Abbrent, S
Lindgren, J
Tegenfeldt, J
Furneaux, J
Wendsjö, Å
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (09) : 3145 - 3149
[2] Abe T., 2002, SYNTHETIC MET, V125, P249
[3] LI+-CONDUCTIVE SOLID POLYMER ELECTROLYTES WITH LIQUID-LIKE CONDUCTIVITY
ABRAHAM, KM
ALAMGIR, M
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (05) : 1657 - 1657
[4] 7Li NMR measurements of polymer gel electrolytes
Adebahr, J
Forsyth, M
MacFarlane, DR
Gavelin, P
Jacobsson, P
[J]. SOLID STATE IONICS, 2002, 147 (3-4) : 303 - 307
[5] Ionic conductivity, DSC and self diffusion coefficients of lithium, anion, polymer, and solvent of polymer gel electrolytes: the structure of the gels and the diffusion mechanism of the ions
Aihara, Y
Arai, S
Hayamizu, K
[J]. ELECTROCHIMICA ACTA, 2000, 45 (8-9) : 1321 - 1326
[6] A flexible Li polymer primary cell with a novel gel electrolyte based on poly(acrylonitrile)
Akashi, H
Tanaka, K
Sekai, K
[J]. JOURNAL OF POWER SOURCES, 2002, 104 (02) : 241 - 247
[7] An ionic conductivity and spectroscopy study of ionic transport mechanism in fire-retardant polyacrylonitrile-based gel electrolytes for Li polymer batteries
Akashi, H
Tanaka, K
Sekai, K
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (03) : 881 - 887
[8] A novel fire-retardant polyacrylonitrile-based gel electrolyte for lithium batteries
Akashi, H
Sekai, K
Tanaka, K
[J]. ELECTROCHIMICA ACTA, 1998, 43 (10-11) : 1193 - 1197
[9] AKASHI H, 1995, POLYM PREP-ACS, V44, P381
[10] AKASHI H, 1997, Patent No. 5658686

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