Structural modification of living polymers: Synthesis of helical block copolymers from a single monomer via palladium-mediated aromatizing polymerization of 1,2-diisocyanobenzenes

被引：20

作者：

Ito, Y ^{[1
]}

Miyake, T ^{[1
]}

Suginome, M ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Kyoto 6068501, Japan

来源：

MACROMOLECULES | 2000年 / 33卷 / 11期

关键词：

D O I：

10.1021/ma991801t

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New optically active helical block copolymers were synthesized by palladium-mediated living sequential copolymerization of 4,5-bis[(tert-butyldimethylsilyloxy)ethoxymethyl]-3,6-dimethyl-1,2-diisocyanobenzene followed by deprotection of the polymer side chains and subsequent structural modification without quenching the living site of the polymer.

引用

页码：4034 / 4038

页数：5

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