A test of J-shifting for H+CO recombination

被引：10

作者：

Qi, JX

Bowman, JM

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

[2] EMORY UNIV,CHERRY L EMERSON CTR SCI COMPUTAT,ATLANTA,GA 30322

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 276卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(97)00833-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We test the J-shifting approximation for H + CO recombination by comparing the recombination rate in the fall-off region against one obtained using accurate J- and K-dependent resonance energies. In applying the J-shifting approximation we consider rotation constants given at the HCO minimum and also at the H-CO saddle point. (C) 1997 Elsevier Science B.V.

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页码：371 / 374

页数：4

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