Phosphorus monoxide as a terminal ligand

被引：50

作者：

Johnson, MJA ^{[1
]}

Odom, AL ^{[1
]}

Cummins, CC ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a703105j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimethyldioxirane oxidation of phosphide PMo[N(R)Ar](3) [R = C(CD3)(2)Me, Ar = C6H3Me2-3,5] efficiently provides (OP)Mo[N(R)Ar](3), a complex shown by X-ray crystallography to contain a terminal phosphorus monoxide ligand, and which reacts with dimethylzirconocene to give addition of a Zr-Me bond across the phosphoryl moiety.

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页码：1523 / 1524

页数：2

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