Intrinsic resonance representation of quantum mechanics

被引:7
作者
Carioli, M
Heller, EJ
Moller, KB
机构
[1] HARVARD SMITHSONIAN CTR ASTROPHYS,CAMBRIDGE,MA 02138
[2] TECH UNIV DENMARK,DEPT CHEM,DK-2800 LYNGBY,DENMARK
关键词
D O I
10.1063/1.473911
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The choice of basis states in quantum calculations can be influenced by several requirements, and sometimes a very natural basis suggests itself. However often one retreats to a ''merely complete'' basis, whose coefficients in the eigenstates carry Little physical insight. We suggest here an optimal representation, based purely on classical mechanics. ''Hidden'' constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leaving the quantum effects to be isolated and included by small matrix diagonalizations. This simplifies the hierarchical structure of couplings between ''zero-order'' states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamilton-Jacobi equation. (C) 1997 American Institute of Physics.
引用
收藏
页码:8564 / 8571
页数:8
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