C-3 symmetric oxazolinyl ligand as catalyst in the enantioselective addition of diethylzinc to aldehydes

被引：29

作者：

Chan, TH

Zheng, GZ

机构：

[1] Department of Chemistry, McGill University, Montreal

来源：

CANADIAN JOURNAL OF CHEMISTRY | 1997年 / 75卷 / 06期

关键词：

diethylzinc; enantioselective synthesis; C-3 symmetric ligands; enantioselective addition reactions; oxazolinyl ligands;

D O I：

10.1139/v97-076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-3 symmetric oxazolinyl ligand 1 has been synthesized. Compound 1 catalyzed the addition of diethylzinc to aromatic aldehydes to give secondary alcohols with high enantiomeric excesses (up to 90%).

引用

页码：629 / 633

页数：5

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