Synthesis and chracterization of heterometallic [Cr7M] wheels

被引：191

作者：

Larsen, FK

McInnes, EJL

El Mkami, H

Overgaard, J

Piligkos, S

Rajaraman, G

Rentschler, E

Smith, AA

Smith, GM

Boote, V

Jennings, M

Timco, GA ^{[1
]}

Winpenny, REP

机构：

[1] Moldavian Acad Sci, Inst Chem, Kishinev, Moldova

[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[3] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

[4] Max Planck Inst Strahlenchem, Mulheim, Germany

[5] Univ St Andrews, Dept Phys & Astron, St Andrews, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 01期

关键词：

D O I：

10.1002/anie.200390034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new set of wheels: Substituting a chromium ion in [Cr8F8(O2CCMe3)16] with one of a number of alternative transition metals has yielded an unprecedented family of heterometallic wheel complexes (see picture), supported at their centers by secondary ammonium ions. Both 3d (Mn, Fe, Co, Ni) and 4d (Cd) metals have been employed to produce such structures, the magnetic and spectroscopic properties of which are discussed.

引用

页码：101 / 105

页数：5

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