Synthesis of carbocycles by enone-selective reduction using organoiodotin hydride

被引：23

作者：

Suwa, T ^{[1
]}

Nishino, K ^{[1
]}

Miyatake, M ^{[1
]}

Shibata, I ^{[1
]}

Baba, A ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mol Chem, Suita, Osaka 5650871, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 18期

基金：

日本学术振兴会;

关键词：

organoiodotin hydride; enone-selective reduction; 1,4-reduction; intramolecular aldol reaction;

D O I：

10.1016/S0040-4039(00)00388-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By using di-n-butyliodotin hydride (n-Bu2SnIH), carbocycles were prepared from substrates hearing both enone and formyl moieties, where the enone-selective reduction was followed by a diastereoselective intramolecular aldol reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3403 / 3406

页数：4

共 11 条

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