Gold catalysis in the reactions of 1,3-dicarbonyls with nucleophiles

被引：197

作者：

Arcadi, A

Bianchi, G

Di Giuseppe, S

Marinelli, F

机构：

[1] Dipto. Chim. Ingegneria Chim. M., Facoltà di Scienze, Univeristà di L'Aquila, 67100 L'Aquila, via Vetoio, Coppito Due

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 01期

关键词：

D O I：

10.1039/b210165c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new efficient gold(III) catalysed synthesis of beta-enaminones from 1,3-dicarbonyl compounds and ammonia/amines providing an attractive and environmental friendly alternative to the more vigorous reagents and drastic conditions of the existing methodologies is described; the catalysis of gold(III) is also extended to reaction of cyclic 1,3-dicarbonyls with O-, P- and S-nucleophiles.

引用

页码：64 / 67

页数：4

共 30 条

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