Modular construction of dendritic carbosilanes. Organization of dendrimer connectivity around bifunctional precursors that are adapted for sequential convergent and divergent propagative steps

被引:7
作者
Casado, MA [1 ]
Stobart, SR [1 ]
机构
[1] Univ Victoria, Dept Chem, Victoria, BC V8W 2Y2, Canada
关键词
D O I
10.1021/ol000038g
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Regiospecific hydrosilylation of 1-bromo-4-(prop-2-enyl)benzene offers an efficient route to molecular building block precursors that can accommodate sequential divergent and convergent steps for dendritic extension, establishing a modular methodology for assembly and organization of connectivity used for synthesis of modified carbosilane dendrimers including 14.
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页码:1549 / 1552
页数:4
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